Portable Instrument for Hemoglobin Determination Using Room-Temperature Phosphorescent Carbon Dots

A portable reconfigurable platform for hemoglobin determination based on inner filter quenching of room-temperature phosphorescent carbon dots (CDs) in the presence of H2O2 is described. The electronic setup consists of a light-emitting diode (LED) as the carbon dot optical exciter and a photodiode as a light-to-current converter integrated in the same instrument. The reconfigurable feature provides adaptability to use the platform as an analytical probe for CDs coming from different batches with some variations in luminescence characteristics. The variables of the reaction were optimized, such as pH, concentration of reagents, and response time; as well as the variables of the portable device, such as LED voltage, photodiode sensitivity, and adjustment of the measuring range by a reconfigurable electronic system. The portable device allowed the determination of hemoglobin with good sensitivity, with a detection limit of 6.2 nM and range up to 125 nM.MINECO (Spain) CTQ2016-78754-C2-1-REuropean Union (EU

Resistive Switching and Charge Transport in Laser-Fabricated Graphene Oxide Memristors: A Time Series and Quantum Point Contact Modeling Approach

This work investigates the sources of resistive switching (RS) in recently reported laser-fabricated graphene oxide memristors by means of two numerical analysis tools linked to the Time Series Statistical Analysis and the use of the Quantum Point Contact Conduction model. The application of both numerical procedures points to the existence of a filament connecting the electrodes that may be interrupted at a precise point within the conductive path, resulting in resistive switching phenomena. These results support the existing model attributing the memristance of laser-fabricated graphene oxide memristors to the modification of a conductive path stoichiometry inside the graphene oxide.The authors thank the support of the Spanish Ministry of Science, Innovation and Universities under projects TEC2017-89955-P, TEC2017-84321-C4-3-R, MTM2017-88708-P and project PGC2018-098860-B-I00 (MCIU/AEI/FEDER, UE), and the predoctoral grant FPU16/01451

Flexible Laser-Reduced Graphene Oxide Thermistor for Ubiquitous Electronics

This work presents a versatile sensing platform, intended for ubiquitous and flexible electronics based on a laser reduced-Graphene-Oxide thermistor. This technique enables the fast and ecological production of reduced Graphene Oxide without the need of masks or expensive lithography processes. The final transducer is fabricated on a flexible plastic substrate in order to use it as a superficial patch. Finally, a full demonstrator, which integrates this flexible thermistor with a low power System on Chip with wireless transmission, is presented.This work has been partially supported by the Spanish Ministry of Education, Culture and Sport (MECD) through the pre-doctoral grant FPU16/01451 , the National Excellence Research Project TEC2017-89955-P and the University of Granada through the scholarship ”Initiation to Research

Screen Printable Electrochemical Capacitors on Flexible Substrates

This work presents a novel approach for the fabrication of Electrochemical Capacitors (ECs) based on the screen-printing of a commercial carbon-based conductive ink on flexible substrates. This technique enables the fast and cost-effective production of ECs with high flexibility and outstanding performance over bending states and voltage cycling, as demonstrated by means of cyclic voltammetry and galvanometric charge-discharge measurements. Despite the fact that the specific areal capacitances achieved are lower than the ones obtained using other carbon-based materials (~22 μF/cm2), the results show that, as soon as new screen-printable carbon-based pastes become available, this fabrication method will enable the mass production of ECs that can be attached to any surface as a conformal patch, as it is being required by a large number of the emerging technological applications.This work has been partially supported by the Spanish Ministry of Education, Culture and Sport (MECD) and the European Union through the pre-doctoral grant FPU16/01451, and its mobility program, the project TEC2017-89955-P and fellowship H2020-MSCA-IF-2017794885-SELFSENS

Laser-Fabricated Reduced Graphene Oxide Memristors

Finding an inexpensive and scalable method for the mass production of memristors will be one of the key aspects for their implementation in end-user computing applications. Herein, we report pioneering research on the fabrication of laser-lithographed graphene oxide memristors. The devices have been surface-fabricated through a graphene oxide coating on a polyethylene terephthalate substrate followed by a localized laser-assisted photo-thermal partial reduction. When the laser fluence is appropriately tuned during the fabrication process, the devices present a characteristic pinched closed-loop in the current-voltage relation revealing the unique fingerprint of the memristive hysteresis. Combined structural and electrical experiments have been conducted to characterize the raw material and the devices that aim to establish a path for optimization. Electrical measurements have demonstrated a clear distinction between the resistive states, as well as stable memory performance, indicating the potential of laser-fabricated graphene oxide memristors in resistive switching applications.This work has been supported by the Spanish Ministry of Science, Innovation and Universities/FEDER-EU through the project TEC2017-89955-P, Iberdrola Foundation under its 2018 Research Grant Program, the pre-doctoral grants FPU16/01451, FPU16/04043, and the JSPS KAKENHI through grant number JP18k04275

Multipurpose Sensing Platform Based on Laser-Reduced Graphene Oxide for Flexible and Ubiquitous Electronics

We present a versatile sensing platform, intended for ubiquitous and flexible electronics sensing applications based on the controlled reduction of Graphene Oxide by a laser diode. This technique allows the fast and ecological production of reduced Graphene Oxide without the need of expensive lithography masks. We will show results of the conductivity calibration by the photothermal reduction power, as well as the electrical characterization of the bare samples. Finally, a simple demonstrator of the platform based on an ultra-low power System on Chip (SoC) is introduced.This work has been supported by the Spanish Ministry of Educaton, Culture and Sport (MECD) through the pre-doctoral grant FPU16/01451, the University of Granada through the scholarship “Initiation to Research“, the National Excellence Research Project TEC2017-89955-P and the European Union by the fellowship H2020-MSCA-IF-2017 794885-SELFSENS

Low-Cost Energy-Autonomous Sensor Nodes Through RF Energy Harvesting and Printed Technology

The irruption of Internet of Things and 5G in our society comes along with several technological challenges to overcome. From an overall perspective, the low-cost and environmental friendliness of these technologies need to be ensured for their universal deployment in different areas, starting with the sensors and finishing with the power sources. To address these challenges, the production and maintenance of a great number of sensor nodes incur costs, which include manufacturing and integration in mass of elements and sub-blocks, changing or recharging of batteries, as well as management of natural resources and waste. In this article, we demonstrate how Radio Frequency Energy Harvesting (RFEH) and printed flexible technology (a growing technology for sensors) can solve these concerns through costeffective mass-production and utilization of energy harvesting for the development of energy-autonomous nodes, as part of a wireless sensor network. We present as illustration a sprayed flexible relative humidity sensor powered with RFEH under the store-and-use principle.This work was partially supported by the ECSEL Joint Undertaking through the Electronic Component Systems for European Leadership Joint Undertaking under grant agreement No 737434. This Joint Undertaking receives support from the German Federal Ministry of Education and Research and the European Union’s Horizon 2020 research and innovation program and Slovakia, Netherlands, Spain, Italy. In addition, the Spanish Ministry of Education, Culture and Sport (MECD) and the European Union supported it through the pre-doctoral grant FPU16/01451 and the fellowship H2020-MSCA-IF-2017794885-SELFSENS

Memcapacitor and Meminductor Circuit Emulators: A Review

This research was funded by the Japanese KAKENHI through Grant Number JP18k04275 and Spanish Ministry of Education, Culture, and Sport (MECD), through Project TEC2017-89955-P and Grant Numbers: FPU16/01451 and FPU16/04043.In 1971, Prof. L. Chua theoretically introduced a new circuit element, which exhibited a different behavior from that displayed by any of the three known passive elements: the resistor, the capacitor or the inductor. This element was called memristor, since its behavior corresponded to a resistor with memory. Four decades later, the concept of mem-elements was extended to the other two circuit elements by the definition of the constitutive equations of both memcapacitors and meminductors. Since then, the non-linear and non-volatile properties of these devices have attracted the interest of many researches trying to develop a wide range of applications. However, the lack of solid-state implementations of memcapacitors and meminductors make it necessary to rely on circuit emulators for the use and investigation of these elements in practical implementations. On this basis, this review gathers the current main alternatives presented in the literature for the emulation of both memcapacitors and meminductors. Different circuit emulators have been thoroughly analyzed and compared in detail, providing a wide range of approaches that could be considered for the implementation of these devices in future designs.Ministry of Education, Culture, Sports, Science and Technology, Japan (MEXT) Japan Society for the Promotion of Science Grants-in-Aid for Scientific Research (KAKENHI) JP18k04275Spanish Ministry of Education, Culture, and Sport (MECD) TEC2017-89955-P FPU16/01451 FPU16/0404

Fabrication of low cost and low impact RH and temperature sensors for the Internet of Environmental-Friendly Things

Given the increasing number of connected devices as a consequence of the Internet of Things (IoT) revolution, the issue of the removal and recycling of electronics is becoming more and more urgent. In this context, biodegradable electronics is expected to be one of the biggest technological revolutions to tackle this problem. Following this direction, in this work we present the fabrication and characterization of temperature and humidity sensors based on biodegradable materials with the goal of making their removal easier as well as reducing their environmental impact. In particular, these multi-sensing devices were fabricated following a screen-printing process using a carbon-based paste and a conjugated polymer, both on paper and on a water soluble substrate. The results are more than promising and show how with our biodegradable sensors it is possible to obtain a sensitivity of 1 dec/20%RH to moisture content and around 0.04%/°C sensitivity to temperature. It is demonstrated that the simplicity and flexibility of the fabrication approach followed in this work paves the way to a set of new “green” IoT nodes that could be extended to wide range of sensing applications

In-Depth Study of Laser Diode Ablation of Kapton Polyimide for Flexible Conductive Substrates

This work presents a detailed study of the photothermal ablation of KaptonR polyimide by a laser diode targeting its electrical conductivity enhancement. Laser-treated samples were structurally characterized using Scanning Electron Microscopy (SEM), Raman spectroscopy, X-ray Photoelectron Spectroscopy (XPS), as well as Diffuse Reflectance Infrared Fourier Transform (DRIFT) spectroscopy. The results show that the laser-assisted ablation constitutes a simple one-step and environmental friendly method to induce graphene-derived structures on the surface of polyimide films. The laser-modified surface was also electrically characterized through the Transmission Line Method (TLM) aiming at the improvement of the conductivity of the samples by tuning the laser power and the extraction of the contact resistance of the electrodes. Once the laser-ablation process is optimized, the samples increase their conductivity up to six orders of magnitude, being comparable to that of graphene obtained by chemical vapor deposition or by the reduction of graphene-oxide. Additionally, we show that the contact resistance can be decreased down to promising values of ~2 W when using silver-based electrodes.This work has been partially supported by the Spanish Ministry of Education, Culture and Sport (MECD), the European Union and the University of Granada through the project TEC2017-89955-P, the pre-doctoral grant FPU16/01451, the fellowship H2020-MSCA-IF-2017 794885-SELFSENS and the grant “Initiation to Research”. Additionally, this work was supported by the German Research Foundation (DFG) and the Technical University of Munich within the Open Access Publishing Funding Programme